Anorthosite. Origin and deposits in Ukraine
Anorthosite is a leucocratic igneous rock of the gabbro group, composed almost entirely of basic and medium plagioclase with a small amount of mafic minerals (such as olivine, pyroxene, magnetite, or titanomagnetite). It occurs in large massifs and dikes. It typically has a dense, massive texture, and its color ranges from light gray to nearly black.
The first scientific description of an anorthosite deposit was made in 1863 by the chemist and mineralogist T. S. Hunt in the American Journal of Science and Arts. In Ukraine, the development of a variety of anorthosite—labradorite—began in 1835 in Volyn at the quarries of Kamianyi Brid and Slobidka. The Holovynske labradorite deposit began to be developed much later, in 1900.
Anorthosite is included in the list of minerals of national importance, approved by Resolution of the Cabinet of Ministers of Ukraine No. 827 of December 12, 1994, as a raw material for facing materials (decorative stone) and as a raw material for rubble stone and crushed stone..
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On Earth, typical nearly pure anorthosite massifs have been identified only within ancient cratons (Ukraine, Canada, Finland), and they are more than 1 billion years old.
Although anorthosites are considered igneous rocks, no complete analogues of volcanics of this chemical composition have been found in nature. Some high-alumina basalts are somewhat similar to them.
The largest anorthosite massifs (covering areas of about or more than 1,000 km²) are spatially and, according to most researchers, genetically associated with large so-called anorthosite–rapakivi granite plutons—as separate independent deep magmatic bodies. Anorthosites also occur as layers of varying thickness within differentiated, predominantly gabbroic and gabbro-peridotite massifs, for example in Bushveld (South Africa), Stillwater (Montana, USA), Skaergaard (Greenland), and Monchegorsk (Kola Peninsula). Such anorthosites are sometimes called autonomous.
In Ukraine, anorthosite deposits are associated with the Korosten and Korsun–Novomyrhorod plutons. There are a number of quarries in the Zhytomyr and Cherkasy regions where anorthosites capable of iridescence—labradorites—are extracted.
Chemical composition
The rock is formed by more than 90% plagioclase (mostly the main composition). Secondary and accessory minerals of anorthosites ― orthopyroxene, less often olivine, clinopyroxene, biotite, ilmenite, magnetite, sulfides, quartz and its subgraphic growth with calispate (granophyre), apatite, zircon.
The name comes from anorthite ― calcium plagioclase CaAl2Si2O8. But in natural rocks called anorthosites, plagioclase most often has an intermediate composition, in which the content of the anorthite component is 40–60 %, less often 70–80 %. Only on the Moon are anorthosites composed of anorthite itself.
Physical properties
Anorthosites are typically characterized by a coarse-grained (0.5–3.0 cm) or pegmatitic structure, with plagioclase crystals that may reach sizes of 10 cm or more. Individual plagioclase crystals are black, white, blue or gray, often showing iridescence — a change in surface color depending on the angle of observation or illumination. Most often, a blue color is observed, less often green, sometimes yellow-orange.
In modern literature, all predominantly plagioclase rocks are classified as anorthosites with possible additional descriptors—labradorite, andesine, bytownite, etc.
Features of the rock: extreme reliability, resistance to moisture, corresponds to the 1st class of radiation safety (which indicates minimal radioactivity of the material), durability, resistance to high and low temperatures, as well as to their differences.
Anorthosite reserves in Ukraine
Ukraine contains about 5% of the world’s reserves of decorative stone, despite occupying only 0.4% of the Earth’s land area. Nearly one-third of this territory (approximately 200,000 km²) belongs to the Ukrainian Shield, where deposits of uniquely colored granites, diorites, labradorites, gabbro, anorthosites, and other varieties of high-quality decorative stone are concentrated.
Among all mineral resources in Ukraine, non-metallic minerals are the most widespread. This is due both to their significant diversity in origin and to the large number of known and already developed deposits.
Rocks of the gabbro–anorthosite complex are most extensively developed in the Zhytomyr region and are associated with the Korosten Pluton, located in the northwestern part of the Ukrainian Shield. The area of distribution of these rocks covers about 800 km².
The Korosten Pluton is one of the largest intrusive rock massifs in the northwestern Ukrainian Shield. The main rocks (occupying about a quarter of the area)—gabbro, gabbronorites, gabbro-anorthosites, and labradorites—form two large and several smaller massifs. Primary and placer deposits of ilmenite and apatite are associated with these gabbroids. In Ukraine, according to the “Geoinform of Ukraine” DNVP, the balance reserves of explored anorthosite deposits amount to 15,248,446 thousand m3. Anorthosite deposits in Ukraine are represented by the following deposits: Torchynske, Andriivske, Kamianobridske, Nikitivske and Lukovetske (Zhytomyr region). Currently, anorthosite is extracted only at three of these deposits: Torchynske, Nikitivske, and Lukovetske.
Uses
The main economic value of anorthosite bodies is titanium-containing ilmenite oxide. However, some Proterozoic anorthosite bodies contain large amounts of labradorite, which is mined for its value both as a gemstone and as a building material. It is used as a facing material in construction inside and outside premises (fireplaces, columns, window sills, countertops). It can be used to make various figures and fakes (vases, devices).
Archean anorthosites contain high amounts of aluminum replacing silicon; some of these bodies are mined as aluminum ores. Anorthosite was widely represented in rock samples brought from the Moon and is important in studies of Mars, Venus, and meteorites.