Vermiculite. Characteristics, distribution, application
Vermiculite is a natural mineral belonging to the hydromica group. It is known for its unique physical and chemical properties, which make it indispensable in many industries, agriculture and construction. The name of the mineral comes from the Latin word vermiculus, meaning ‘worm,’ due to vermiculite’s characteristic ability to expand under the influence of high temperatures and take on a shape similar to small worms.
Vermiculite is included in the list of minerals of national importance approved by Resolution of the Cabinet of Ministers of Ukraine No. 827 of 12 December 1994 as an adsorbent raw material.
List of minerals of national importance
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Go to the listComposition and properties
Vermiculite is an aluminosilicate of magnesium, iron and aluminium with a unique layered structure. Vermiculite contains a significant amount of magnesium (10–14%) in the form of magnesium aluminosilicates, 3–5% potassium, 1.2–2% calcium and trace elements: chromium, nickel, manganese, cobalt, copper, molybdenum.
Chemical formula Mg₀.₇(Mg,Fe,Al)₆(Si,Al)₈O₂₀(OH)₄ * 8H₂O
Vermiculite has a monoclinic crystal structure. It has perfect cleavage. Its density is 2.4–2.7. Hardness on the Mohs scale of mineral hardness — 1–1.5. Colour is brown, yellowish-brown, golden-yellow, sometimes with a greenish tint. Lustre is pearly or greasy. It has a high cation exchange capacity.
The most important property of vermiculite is its ability to expand when heated to a temperature of 900‑1000°C, increasing in volume by 15–20 times, which leads to an expansion of the adsorption surface. Due to its specific porosity, adsorption and ion exchange properties, expanded vermiculite is capable of selectively absorbing certain substances and cations, especially potassium and ammonium, which it then slowly releases to plants, acting as a prolonged macro- and microfertiliser. The process of fixing ammonium, mobile forms of nitrogen, magnesium, phosphorus and potassium in the soil with vermiculite is widely studied by scientists in many foreign countries.
Other properties of the mineral:- Thermal insulation: Vermiculite has low thermal conductivity, making it ideal for use in thermal insulation materials.
- Fire resistance: The mineral can withstand temperatures up to 1000 °C without releasing toxic substances.
- Chemical neutrality: The mineral is resistant to acids and alkalis.
- Environmental friendliness: It is a natural material that does not harm the environment.
Distribution in Ukraine
In Ukraine, vermiculite is found in the regions of Volyn, Kirovohrad and Zaporizhzhia regions.
There are more than 50 known vermiculite deposits in Ukraine, most of which are concentrated within the Ukrainian Shield. The Kamianomohylsk deposit was found in the Azov block, and 14 promising areas with P1 and P2 resources totalling 32.8 million tonnes were discovered in the central part of the Ukrainian Shield. These deposits are associated with the weathered crusts of gabbroids and gneisses. The Slavgorod, Lipovenkovsky and Kolarovsky occurrences were also discovered in the Volyn block, but they are not of industrial significance.
The Kamianomohylskyi occurrence is represented by weathering crust on metabasites and biotite gneisses of the Mangus complex. The occurrence is located near the village of Nazarivka in the Volodarsky district of the Donetsk region within the Kamyani Mohyly reserve. The productive horizon has an average thickness of 10.3 m, with a hydrobiotite and vermiculite content of 16.01%. The total vermiculite resources of this deposit are estimated at 1,860 thousand tonnes. The Andriivskyi deposit is formed by weathering crust on ultrabasic rocks, biotite and amphibole-biotite gneisses. The thickness of the ore horizon reaches 14.1 m, the average content of vermiculite in the rock is 25%, and hydrobiotite is 31.8%. The total resources of hydromica amount to 848 thousand tonnes.
The Rodionivsky deposit is located on the right bank of the Berdyansk Reservoir between the villages of Osipenko and Rodionivka in the Berdyansk District of Zaporizhzhia Region. It is characterised by weathering crust on biotite, garnet-biotite, silimanite-biotite and muscovite-biotite schists with amphibolite lenses. The thickness of the ore horizon is 12 m, with a roof thickness of 10.1 m. The content of hydrobiotite in the ore is 22.4%, vermiculite — up to 1%. The ore also contains quartz, plagioclase, muscovite, chlorite, garnet and hornblende.
The Slavgorod occurrence is located near the town of Slavgorod in the Simelnikovo district of Dnipropetrovsk region, in hyperbasites of the Aul series, where they come into contact with gneisses. This zone extends for 1 km in length and up to 200 m in width, and the thickness of vermiculite-bearing layers is 10–30 m. The content of vermiculite and hydrobiotite reaches 25%, and the estimated reserves are estimated at 700 thousand tonnes. The Lipovenkovsky deposit is represented by five vein-like bodies in the hyperbasite massif. The length of these bodies is 70–160 m, the thickness is 3–8.5 m, and the hydromica content ranges from 40–80%. The estimated reserves of vermiculite are 190 thousand tonnes, and those of hydrobiotite are 97 thousand tonnes.
Lypovenky deposit, located near the village of Lypovenky in the Golovanivskyi district of the Kirovohrad region. The productive part of the deposit is the weathered crust of serpentinites, serpentinised peridotites, as well as tremolites and actinolites, which are associated with 5 vermiculite-bearing vein-like bodies with a length of 60–170 m and a thickness of 3–8.5 m. The estimated reserves of vermiculite at the deposit are 190 thousand tonnes, and those of hydrobiotite are 97 thousand tonnes.
The Kolarivsky deposit contains vermiculite-bearing weathering crust on lamproites, with an average productive layer thickness of 19.3 m. The vermiculite content is 22.5%, and the estimated reserves of this deposit are estimated at 700 thousand tonnes.
In addition, in the south-western part of the Ukrainian Shield, in particular in the Raigorodskaya, Yurkovskaya and Dzhurinskaya areas, geological exploration work was carried out with the aim of increasing the mineral resource base of vermiculite. Exploration work was also carried out in the Zakarpattia and Donetsk regions, which also have prospects for the discovery of deposits of this raw material.
Uses of vermiculite
Vermiculite has a wide range of applications due to its unique properties. It is used as a lightweight filler for concrete, a raw material for the manufacture of refractory materials, heat and sound insulation elements, as well as for fire-resistant plasters and thermal insulation of metallurgical furnaces. In addition, vermiculite is used in the production of anti-friction materials, plastics, pesticides, rubber products, and paints. In agriculture, this mineral is used to improve soil structure. It is also used in the disposal of radioactive waste, wastewater treatment, as well as in space technology, the aerospace industry, and transport construction.
One of the key properties of this mineral is thermal insulation. Due to its low thermal conductivity, vermiculite is used in the manufacture of thermal insulation materials. It is also highly fire-resistant, withstanding temperatures of up to a thousand degrees without releasing toxic substances.
Its chemical neutrality and ability to retain moisture make it popular in agriculture. For example, in plant cultivation, it is added to soils or substrates to retain moisture and minerals, which promotes healthy crop growth. Acting as a magnesium fertiliser, vermiculite releases the element needed by plants and gradually releases it, which is of great practical importance, especially for areas where sod-podzolic sandy and sandy loam soils prevail, which are deficient in magnesium.
Vermiculite is also widely used in construction. It is used as insulation in building structures and added to concrete mixtures to reduce their weight and improve their thermal insulation properties. Due to its fire resistance, it is indispensable in the manufacture of protective coatings for metal structures, as well as in the construction of fireplaces and chimneys.
In addition, vermiculite is in demand in industry as an absorbent, filter material and component for refractory products. It is lightweight, durable, environmentally friendly and suitable for reuse, making it the optimal choice for many needs.
In summary, vermiculite combines environmental friendliness, versatility, and ease of use, ensuring its popularity in various industries. If you need a reliable material for specific tasks, vermiculite is an excellent choice.
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